Emission Lifetime(s) of Ru(bpy)32+ in Zeolite Y Under Various Loadings of Ru(II) Complex and TiO2.
% Ru(bpy)32+a,b |
% TiO2a |
t1 / ns |
Ac |
t2 / ns |
Bc |
6.2 |
0 |
412 |
96 |
54 |
4 |
12.4 |
0 |
369 |
98 |
52 |
2 |
17.9 |
0 |
283 |
87 |
60 |
12 |
23.3 |
0 |
141 |
70 |
40 |
30 |
6.2 |
9.5 |
137 |
68 |
37 |
32 |
10.8 |
9.4 |
456 |
95 |
59 |
5 |
17.6 |
9.8 |
385 |
93 |
60 |
7 |
21.9 |
9.4 |
278 |
97 |
67 |
3 |
23.2 |
17.3 |
228 |
81 |
59 |
18 |
22.9 |
24.2 |
219 |
75 |
57 |
25 |
22.9 |
27.2 |
205 |
100 |
||
22.7 |
31.2 |
227 |
100 |
||
22.5 |
31.8 |
243 |
100 |
||
22.4 |
34.6 |
266 |
100 |
||
22.1 |
37.1 |
274 |
100 |
aPercent by weight. b25.1% loading represents one Ru(bpy)32+ complex in each supercage. cDecays fit to [Aexp(t/t1) + Bexp(t/t2)].